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nitrite reductase
Nitrite reductase refers to any of several classes of enzymes that catalyze the reduction of nitrite. There are two classes of NIR's. A multi haem enzyme reduces NO2− to a variety of products. Copper containing enzymes carry out a single electron transfer to produce nitric oxide.
== Iron based ==
There are several types of iron based enzymes. Cytochrome cd1, or ''Pseudomonas'' cytochrome oxidase contains two c and two d type hemes with two polypeptide chains. Different forms of this reductase catalyze the formation of nitric oxide or nitrous oxide.〔 A version of this compound was originally called (c-551:oxidoreductase ). It was initially considered an oxidase. It catalyzes the reduction of NO2− to NO. This tetraheme enzyme has two subunits, each containing a c-type and a d-type heme. The reduced d hemes bind nitrite and convert it to product.
Cytochrome c nitrite reductase (ccNIR) is a multiheme enzyme that converts nitrite to ammonia on each active site. The active site iron is bound to a protoporphyrin IX ring that is covalently linked to the enzyme's proteins.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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